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The internally programmed two-injection method for determining the dissolved air correction in the CCA-VP laboratory vapor pressure instrument (Grabner Instruments), while adequate for pure, single component liquids, can be in error for full boiling range automotive fuels. For these fuels, errors of up to 10 kPa (1.5 psi) in vapor pressure at 38°C (100°F) can occur due to the increase in vapor pressure between the first and second injection caused by decreasing vapor liquid ratio (V/L); this increase is interpreted by the instrument as additional dissolved air and results in overcorrection for this effect. A method is demonstrated for removing the V/L effect using two TV/L values for the subject fuel, either calculated or measured independently. The true air correction determined in this way is similar to values obtained for single component fuels and to values calculated directly from air solubility data.

A cylindrical combustion bomb with dynamic charging system and electro-hydraulic sampling valve is used to study the effects of turbulence on hydrocarbon (HC) emissions from a quench layer and from artificial crevices. The turbulence level is varied by changing the delay time between induction of combustible charge and ignition. Propane-air mixtures were studied over an initial pressure range of 150 to 500 kPa and equivalence ratios of 0.7 to 1.4. Sampling valve experiments show that quench-layer fuel hydrocarbons are extensively oxidized within 5 ms of flame arrival under laminar conditions and that turbulence further reduces the already low level. Upper limit estimates of the residual wall layer HC concentration show that residual quench layer hydrocarbons are only a small fraction of the exhaust HC emission.