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The removal of tetraethyl lead (TEL) from U.S. automotive gasoline has caused concern within the general aviation (GA) community because of possible legislated environmental or supply restrictions on TEL, an essential ingredient in existing high octane aviation gasolines (avgas). At the same time, the GA industry which was besieged by numerous product liability suits in the past has seen a resurgence since the passage of the GA Revitalization Act in 1994. Because aircraft typically remain in service for many years, the survival of the industry may well depend on the availability of a high octane unleaded gasoline that provides a safe level of power and antiknock performance to the existing fleet. This paper describes the tools and techniques used by one team to develop fuels that provide the required antiknock quality while meeting most of the other criteria of the existing specification for high octane avgas: ASTM D 910, Standard Specification for Aviation Gasolines.

Nitrogen compounds present in mineral base oils at low concentrations are known to accelerate oil oxidation and to reduce the useful lifetime of formulated lubricants. Both Partial Least Squares and Neural Network analyses were employed to establish correlations between base oil composition and performance in industry standard thermal stability and oxidation tests. These correlations show that the “basic nitrogen” (BN) content of a base oil is a very important compositional feature determining its ultimate performance in a formulated lubricant which may be especially important for API Group II and III base oils that are relatively free of other pro-oxidants and naturally occurring, sulfur-containing antioxidants. The effect of BN species was also studied using model nitrogen compounds and it was confirmed that the pro-oxidant effect appears only in “basic” nitrogen containing molecules involving pyridine and quinoline derivatives.