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Technical Paper

The Effect of Gasoline Composition on Stoichiometry and Exhaust Emissions

1994-10-01
941868
Six full range gasolines were tested in two engines (one with a catalyst) operated at 4 steady states. Engine-out regulated emissions responded to equivalence ratio, Φ, in the accepted manner. For both CO and NOx, there was a characteristic, single emissions response to changes in Φ. Changing fuel composition will primarily alter the production of these emissions by modifying the stoichiometric air/fuel ratio, projecting engine operation onto another part of the Φ response curve. These Φ effects, which are independent of engine design, also determine how operating conditions affect engine-out CO and NOx. Speciated hydrocarbon measurements at engine-out and tail-pipe confirm results seen in previous test-cycle based programmes.
Technical Paper

An Integrated Study of the Effects of Gasoline Composition on Exhaust Emissions Part I: Programme Outline and Results on Regulated Emissions

1993-10-01
932678
Following a small scouting programme to examine the scale of emissions benefits achievable by different degrees of gasoline base fuel redesign (SAE 930372), a larger programme has been initiated to investigate more systematically the influence of individual fuel parameters on tailpipe emissions. This coordinated study has been spread across five participating Shell Group laboratories, using a set of common fuels specifically designed and centrally blended for this purpose. Additionally, subsets of these fuels have been used for detailed systematic examination of selected topics within the overall programme scope. This paper summarises the plan for the integrated study. It describes the composition and properties of the fuels and their blending. The results covered here are those of chassis dynamometer-based regulated emissions studies conducted on a composite fleet designed to represent a range of vehicle technologies, using a variety of regulatory driving cycles.
Technical Paper

Effect of Gasoline Reformulation on Exhaust Emissions in Current European Vehicles

1993-03-01
930372
As a first attempt to assess the scope for reducing the emissions from gasoline fuelled vehicles in the European market via fuel changes, an experimental scouting programme has been conducted to examine the effects of fuel composition and properties on both regulated emissions and detailed exhaust gas composition. This 4 fuels/4 vehicles programme involved exhaust emission tests on a chassis dynamometer, and was carried out mainly on non-catalyst vehicles, using two commercial gasolines and two (“reformulated”) test gasolines representing “intermediate” and “extreme” changes of the base gasoline design. The fuel characterization includes analysis by hydrocarbon type and carbon number; the exhaust analysis comprises both regulated emissions and hydrocarbon speciation measurements. In the case of regulated emissions, the fuel effects are, as expected, relatively small in comparison with the effect of installing exhaust catalysts.
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