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A spectroscopic trace gas sensor using a distributed feedback diode laser at λ=1.53 µm and based on quartz enhanced photoacoustic spectroscopy technique is described. The sensor is capable of quasi-simultaneous quantification of trace ammonia, hydrogen cyanide, and acetylene (NH3, HCN, and C2H2, respectively) concentrations at ∼100 ppbv levels with a 4s integration time. The sensor design, responsivity, noise, and cross-talk characteristics are reported.

NH3 and CO2 concentration measurements performed on a Biological Water Processor (BWP), under development at NASA-JSC for water recycling, using near infrared laser diode absorption spectroscopy are reported. The gaseous effluents from the bioreactor are a concern for potentially introducing harmful amounts of NH3 in a spacecraft environment. Furthermore, NH3 and CO2 monitoring is important for understanding the nitrogen and total organic carbon (TOC) balance and conversion dynamics in the BWP, and real time continuous monitoring could reveal dynamic situations that are hard to detect otherwise. Diode lasers operating at wavelengths that access NH3 and CO2 absorption lines near 1.53 μm and 1.99 μm are used in a portable and automated gas sensor system. Concentration measurements were performed during a 16 day period starting in August 25, 2000, and a 5 day period starting in November 10, 2000.