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Technical Paper

Prediction of Viscosity-Shear Properties for VI Improved Crankcase Oils

1994-03-01
940819
This study evaluates the shear-thinning effects of a commercial Viscosity Index (VI) improver in a variety of mineral oil base stocks to produce a series of viscosity grades from 0W-20 to 20W-50. All of these fluids also include a DI package in addition to an olefin copolymer VI improver and base oil. The Penn State high shear capillary viscometer was used to collect the primary data at shear rates of up to 106 s-1 and at 10 to 177°C. Data are fitted to a double truncated power law model to determine the incipient non-Newtonian shear rate Υ̇1, the power law index n, and the incipient second Newtonian shear rate Υ̇2. These parameters are found to be smooth functions of temperature and polymer concentration in the different base stocks. Using the data obtained from OW-20, 10W-30, and 20W-50 SAE grade formulations, these parameters (Υ̇1, Υ̇2 and n) are correlated as functions of temperature, polymer concentration, and a viscosity temperature property of the base oil.
Technical Paper

Prediction of High Temperature Viscosities of Polymer Solutions up to 107 sec-1 Shear Rates

1991-10-01
912411
The Penn State high shear viscometer has been used to measure viscosities of polymer solutions at shear rates up to 106 sec-1 over a temperature range of 20°C to 175°C. A double truncated power law model has been developed for analysis of the primary data from the viscometer. This model can be used to determine the shear rate at which incipient non-Newtonian behavior occurs, the power law index, and the shear rate at which a second Newtonian region is found. These three parameters appear to be regular functions of temperature for a given polymer (Viscosity Index Improver) type. The correlation of these three functions with temperature provides a convenient method of predicting viscosity properties of polymer solutions at various temperatures and shear rates up to 107 sec-1. The Penn State high shear viscometer has been used to evaluate methacrylate and olefin copolymer VI improvers in mineral oil base stocks at shear rates of 106 sec-1 at various temperatures.
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