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This program examined the PAH emissions from two diesel engines representing state-of-the-art technology. One heavy-duty engine, a DDC Series 60, used in highway trucks, and one medium-duty engine, Navistar DTA-466, used in pick-up and delivery type vehicles. The medium-duty engine was tested for engine out emissions and with two different sized exhaust oxidation catalysts. Both of the catalysts were composed of a ceramic monolith coated with a palladium type catalyst. Both engines were tested according to the US EPA transient emissions test on a series of diesel fuels blended with varying aromatics and PAH contents to determine the impact of fuel quality on emissions. All diesel fuels had a low sulphur content (<0.05%) to minimize the formation of sulphate. The particulate matter was collected on teflon-coated filters, backed up with polyurethane foam filters to capture the vapour phase PAH.

The method of flame ionization was used for measuring total hydrocarbons in both single-cylinder and multicylinder 4-cycle, direct injection diesel engine exhaust. Use of the emission parameters of hydrocarbon concentration, per cent unburned fuel, specific hydrocarbon rate, mass of hydrocarbons per million cycles, mass of hydrocarbons per mile, and mass of hydrocarbons per ton-mile are discussed. The basic approach used in the flame ionization detector is shown. The hydrocarbon sample was transferred from the exhaust system through a heated sample line and oven operating at 375 F. The sample line was aspirated to reduce the sample residence time to 2 sec. The effect various sampling locations have on hydrocarbon measurements from a single-cylinder engine is shown and discussed. The effects of load, speed, and injection timing on hydrocarbon emission data are shown for a single-cylinder engine.