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A fuel cell is an electrochemical engine which converts fuel and oxidant electrochemically into water, other chemical products and electricity. At present, depending on the electrolytic conducting media, five fuel cell types are recognized, the alkaline fuel cell (AFC), the proton exchange membrane fuel cell (PEMFC), the phosphoric acid fuel cell (PAFC), the molten carbonate fuel cell (MCFC), and the solid oxide fuel cell (SOFC). Various types of hydrogen containing fuels can be used in any of the fuel cells, however only the hydrogen-air fueled fuel cell operating at low to medium temperatures (0-450 C) can be considered to meet the zero emission vehicle (ZEV) requirements. Byproducts of the electrochemical reaction of the fuel cells when hydrocarbons and air are used include carbon monoxide, carbon dioxide and at higher temperatures nitrogen oxide.

A fuel cell (FC) powerplant is an electrochemical engine that converts fuel and an oxidant electrochemically into electric energy, water and other chemical byproducts. When hydrogen is used as the fuel, the only products of the electrochemical reactions are water and electric power. Other conventional and advanced powerplants for transportation, such as the internal combustion (IC) engine, the Diesel engine and others, are thermal combustion engines. The theoretical or thermodynamic efficiency of a fuel cell or electrochemical engine is much higher than the thermodynamic efficiency of a heat engine. The practical efficiency of a fuel cell is highest at partial load, whereas the practical efficiency of a heat engine is highest at maximum power. A survey is presented of the different fuel cell types and their characteristics. The proton-exchange-membrane (PEM) fuel cell is shown to be the best available fuel cell for transportation applications.