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It can be said that the greatest engineering challenge of mobility it is not related to the energy shortage, but to its generation and sustainable use. In this context, the growing use of biofuels by high performance internal combustion engines represents a sustainable alternative from the economic, technological, social and environmental point of view. In some regions of the planet, the modern electric and hybrid vehicles may not be the most sustainable choice, since they face many obstacles regarding clean energy generation, reduced recharging station network, limited autonomy, expensive vehicle prices, and battery recycling. In Brazil since its launching in 2003, the fleet of Flex-Fuel vehicles moved by either ethanol or gasoline is ever increasing. It is worth mentioning that the biofuel has physical and chemical properties that could make its use more efficient than it is nowadays.

Recently many government Acts (Inova Energia, Inovar-Auto, RenovaBio) [1, 2, 3] have been implemented in order to expand the use of biofuels in Brazil. Besides the fulfillment until 2030 of the commitment assumed at the COP21[4] to reduce in 43% the gas emission contributing to the greenhouse effect, the expansion of the use of biofuels is important to assure regularity in the supply of fuels to the automotive sector in the next 15 years. In this context, it is worth mentioning a special characteristic of the Flex-Fuel engines that equip the majority of the automobiles in Brazil since their launching in 2003. The maximum compression ratio of these engines depends on the knocking characteristics of the gasoline, but usually an intermediate value, nearer to the ideal value for gasoline, is a compromise.