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Atmospheric corrosion of steels, aluminum alloys, and Al-clad aluminum alloys is a problem for many civil engineering structures, commercial and military vehicles, and aircraft. Paint is usually the primary means to prevent the corrosion of steel bridge components, automobiles, trucks, and aircraft. Under ideal conditions, the coating provides a continuous layer that is impervious to moisture. At present, maintenance cycles for commercial and military aircraft and ground vehicles, as well as engineered structures, is based on experience and appearance rather than a quantitative determination of coating integrity. To improve the maintenance process and reduce costs, sensors are often used to monitor corrosion. The present suite of sensors designed to detect corrosion and marketed to predict the lifetime of the engineered components, however, are not useful for determining the condition of the protective paint coatings.

The electrochemical and corrosion behavior of metals in aqueous environments has received substantial attention. However, relatively little work has been devoted to the electrochemistry and corrosion of metals in non-aqueous environments. Now, with greater pressures to increase fuel efficiencies and decrease exhaust emissions, alternatives and additives to gasoline (including methanol and ethanol) are receiving increased attention from government agencies and automobile manufacturers. Unfortunately, fundamental studies of the corrosion behavior of metals in these solutions are scarce. The objective of the present work is to investigate the electrochemical and corrosion behavior of iron in methanolic solutions containing Cl, H+, SO42-, and H2O. To accomplish this, a full factorial design test matrix was developed to systematically evaluate the effects of these impurities on the corrosion behavior of iron.