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The internally programmed two-injection method for determining the dissolved air correction in the CCA-VP laboratory vapor pressure instrument (Grabner Instruments), while adequate for pure, single component liquids, can be in error for full boiling range automotive fuels. For these fuels, errors of up to 10 kPa (1.5 psi) in vapor pressure at 38°C (100°F) can occur due to the increase in vapor pressure between the first and second injection caused by decreasing vapor liquid ratio (V/L); this increase is interpreted by the instrument as additional dissolved air and results in overcorrection for this effect. A method is demonstrated for removing the V/L effect using two TV/L values for the subject fuel, either calculated or measured independently. The true air correction determined in this way is similar to values obtained for single component fuels and to values calculated directly from air solubility data.

The aldehyde emissions of 1.6L and 5.0L flexible fuel vehicles (FFV) have been measured, with and without a catalyst, on a range of fuels. The “zero mile” catalyzed emission levels of formaldehyde when operating on M85 (85% methanol and 15% gasoline) are in the 5-15 mg/mi range, but as mileage accumulates they tend to be in the 30-50 mg/mi range. The feedgas levels are high and appear to correlate with engine displacement. The formaldehyde and methanol emissions are higher when operating on M100, compared to M85, but the non-oxygenated hydrocarbon emissions are about the same for both fuels, which suggests that the use of M85 may actually provide more air quality benefit than M100. High mileage control of aldehydes to the level of gasoline vehicles does not appear possible with current technology.