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This work presents an application of the simulated annealing algorithm to redundant system reliability optimization, and its objective is to analyze this method and compare to other optimization methods, which are Genetic Algorithm, Evolution Strategy and Lagrange Multipliers. A hidrid optimization algorithm, composed by Simulated Annealing and Genetic Algorithm, is also developed in this work, to conciliate the advantages of both methods. The results presented by the Simulated Annealing and the hybrid algorithm are significant and validate these methods as robust tools for parameters optimization in engineering systems developments