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Technical Paper

The Ignition and Combustion of Cerium Doped Diesel Soot

1999-03-01
1999-01-0115
Particulates (soot) were sampled from the regenerative trap of an automotive diesel engine run under three speed/load conditions. The fuel was doped with a cerium-based catalyst to promote oxidation of the soot bed. The soots were subjected to combustion testing in a DTG under both temperature ramping and isothermal conditions, and under temperature ramping in a small fixed bed. The combustion gas was 10% oxygen in nitrogen, which was supplemented in the case of the fixed bed with other gases found in diesel exhausts. The temperatures of initiation of combustion Tin were measured in the DTG and in the fixed bed. The kinetic rates of oxidation were calculated from the DTG results taking into account the influence of oxygen transport. The effect of gas composition on ignition and burnout in the fixed bed was determined. Ignition did not occur in the DTG, but rather burning progressed steadily.
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