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Recreational marine engine operation effects water quality as well as air quality. Significant quantities of hydrocarbons are discharged into the rivers, lakes, and estuaries used as recreational boating waters. In order to investigate the impact of recreational marine engine operation on water quality, a MerCruiser 3.0LX four-cylinder four-stroke inboard engine and a Mercury 650 two-cylinder two-stroke outboard engine were tested using EPA required certification procedures. Both engines were tested with exhaust gas/cooling water mixing (scrubbing) in the exhaust stream using both freshwater and saltwater. Additionally, the inboard engine was tested without exhaust scrubbing. Gaseous emissions (HC, NOX, CO, and CO2) from the engines were continuously measured using a constant volume sampling system. Both exhaust gas and cooling water samples were collected and speciated for hydrocarbon species present.

A research program at West Virginia University sought to identify and quantify the individual hydrocarbon species present in alternative fuel exhaust. Compressed natural gas (CNG) has been one of the most widely researched fuels proposed to replace liquid petroleum fuels. Regulated CNG non-methane hydrocarbon emissions are often lower than hydrocarbon emissions from conventional liquid fuels because of the absence of heavier hydrocarbons in the fuel. Reducing NOx and non-methane organic gas (NMOG) emission levels reduces the ozone forming potential (OFP) of the exhaust gases. A Hercules GTA 3.7 liter medium duty CNG engine was operated at seven load and speed set points using local supply CNG gas. The engine was operated at several rated, intermediate and idle speed set points. The engine was operated while the air/fuel ratio value was varied.