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The after-treatment of exhaust gas using 3-way catalytic converters is now normal practice in automotive applications. For other applications, such as outboards, motorcycles and utility engines, new legislation is now in place in both Europe and North America. Further reduction of the permitted emission levels require the use of catalysts for two-stroke engine applications. However, current automotive catalyst systems are not suitable for durable operation in most two-stroke engines and new analytical tools are required to aid the development engineers in the implementation of revised designs and operating strategies. This paper reviews the range of modeling techniques which have been developed for automotive uses and presents new and modified models suitable for two-stroke engines. This requires particular emphasis to be placed on the oxidation reactions that predominate in the two-stroke engine exhaust.

Previously, an initial investigation examined the effect of the catalytic substrate on the gas dynamics of the blowdown pulse on the QUB single shot rig. This initial investigation measured the resulting waves from the catalytic converter in the exhaust pipe. In this early study the substrate was at ambient temperature but it is recognised that after light-off higher reaction temperatures will result from the exothermic nature of exhaust gas oxidation and reduction. Therefore substantially different results will occur. This paper details a series of experiments which investigate the influence of an operating catalyst on the unsteady gas dynamics in an exhaust system using the QUB single shot rig. In addition to measuring the effect of temperature on the gas dynamics previous work is reviewed with emphasis now on specifically measuring the features present rather than having to decipher superimposed pressure traces.

The continued pursuit in Europe for lower emissions from transport vehicles now identifies several new areas to be targeted as their total emissions become ever more significant when compared to the continued decrease in automotive emissions. One such transport area that now faces pressure in the reduction of exhaust emissions, is the scooter/ moped market. The new ECE R47 cycle that governs the operational mode of the vehicle specifies a typical driving cycle over which the total emissions are collected and analysed. This paper evaluates a carburetted 50 cc moped over such a cycle and from the results ascertains the possibility of catalysing the exhaust gas to achieve acceptable limits. An empirical catalyst model is used to predict exhaust gas and substrate bed temperatures with the view to prolonging durability of the catalyst support. Results are presented for operating strategies which offer better long-term durability.

A mathematical model has been developed which predicts the tailpipe exhaust emissions of two-stroke cycle engines utilising an oxidising catalytic converter. This model is currently one-dimensional and has been developed as an aid to the design of engine/exhaust systems. The experimental rig employed has a two-fold function, its primary task was to aid in the validation of the model. Secondary to this it was used to simulate the gaseous properties of the exhaust gas at various positions in the exhaust system. The validation exercise is currently proceeding utilising metallic substrate technology with preliminary results indicating that the model is showing good correlation to measured values.