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Experiments were performed to measure the average and time-resolved particle number emissions and number-weighted particle size distributions from a gasoline direct injection (GDI) engine. Measurements were made on a late model vehicle equipped with a direct injection spark ignition engine. The vehicle was placed on a chassis dynamometer, which was used to load the engine to road load at five different vehicle speeds ranging from 13 - 90 km/hr. Particle number emissions were measured using a TSI 3020 condensation nucleus counter, and size distributions were measured using a TSI 3934 scanning mobility particle sizer. Average polydisperse number concentration was found to increase from 1.1 × 108 particles/cm3 at 13 km/hr to 2.8 × 108 particles/cm3 at 70 km/hr. Under a closed-loop, stoichiometric homogeneous charge operating mode at 90 km/hr, number emissions fell to 9.3 × 107 particles/cm3 (at all other operating conditions, the engine was in a lean stratified charge operating mode).

Experiments were undertaken to determine some of the characteristics of exhaust particulate emissions in two port fuel injected spark ignition engines. A 2.3L 1993 GM Quad-4 engine and a 4.6L 1994 Ford V8 were tested. Sampling and dilution were accomplished through the use of a single-stage, low residence-time ejector diluter; dilution ratios were maintained at approximately 15:1. Number concentration was measured with a TSI 3020 condensation nucleus counter, and size distributions were measured using two scanning mobility particle sizers. The Quad-4 engine was used to determine the effects of the catalytic converter and deposit control additives on particulate emissions. The catalyst was found to remove particles with an efficiency as high as 78% at low power conditions (∼7 kW), dropping steeply with power, reaching a minimum value of approximately 10% at moderate power conditions (∼18 kW).

Exhaust particulate emissions from a 4-cylinder, 2.25 liter spark ignition engine were measured and characterized. A single-stage ejector-diluter system was used to dilute and cool the exhaust sample for measurement. The particulate measurement equipment included a condensation nucleus counter and a scanning mobility particle sizer. Exhaust measurements were made both upstream and downstream of the catalytic converter using three different fuels. Unlike particulate emissions in diesel engines, spark ignition exhaust particle emissions were found to be highly unstable. Typically, a stable “baseline” concentration on the order of 105 particles/cm3 is emitted. Occasionally, however, a “spike” in the exhaust particle concentration is observed. The exhaust particle concentrations observed during these spikes can increase by as much as two orders of magnitude over the baseline concentration.

Exhaust particle number concentrations and size distributions were measured from the exhaust of a 1995 direct injection, Diesel engine. Number concentrations ranged from 1 to 7.5×107 particles/cm3. The number size distributions were bimodal and log-normal in form with a nuclei mode in the 7-15 nm diameter range and an accumulation mode in the 30-40 nm range. For nearly all operating conditions, more than 50% of the particle number, but less than 1% of the particle mass were found in the nuclei mode. Preliminary indications are that the nuclei mode particles are solid and formed from volatilization and subsequent nucleation of metallic ash from lubricating oil additives. Modern low emission engines produce low concentrations of soot agglomerates. The absence of these agglomerates to act as sites for adsorption or condensation of volatile materials makes nucleation and high number emissions more likely.