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The performance of two catalyst preparations, styled base and base/noble, were determined employing a simulated mining vehicle loading cycle. Such cycles are characterized by sufficiently high exhaust temperatures to cause auto-regeneration of the filter units when these catalyst preparations are employed. Such loading is exhibited in raining service by some moderate and most high production load-haul-dump vehicles plus some haulage trucks. These preparations were shown to be capable of depressing the nominal, ‘untreated’ steady-state minimum soot ignition temperature of approximately 500°C (932°F), to a range varying from 395°C to 424°C (743°F to 797°F). Results of gaseous constituent analyses, particulate determinations, polynuclear aromatic hydrocarbon sampling, catalytic sulphur conversion (SO2 to H2SO4) and Ames testing are presented for the two catalyst preparations studied.

This program examined the PAH emissions from two diesel engines representing state-of-the-art technology. One heavy-duty engine, a DDC Series 60, used in highway trucks, and one medium-duty engine, Navistar DTA-466, used in pick-up and delivery type vehicles. The medium-duty engine was tested for engine out emissions and with two different sized exhaust oxidation catalysts. Both of the catalysts were composed of a ceramic monolith coated with a palladium type catalyst. Both engines were tested according to the US EPA transient emissions test on a series of diesel fuels blended with varying aromatics and PAH contents to determine the impact of fuel quality on emissions. All diesel fuels had a low sulphur content (<0.05%) to minimize the formation of sulphate. The particulate matter was collected on teflon-coated filters, backed up with polyurethane foam filters to capture the vapour phase PAH.