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In order to deeply investigate and improve the complete path from biofuel production to combustion, the cluster of excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Recently, new pathways have been discovered to synthesize octanol [1] and di-n-butylether (DNBE). These molecules are identical in the number of included hydrogen, oxygen and carbon atoms, but differ in the molecular structure: for octanol, the oxygen atom is at the end of the molecule, whereas for DNBE it is located in the middle. In this paper the utilization of octanol and DNBE in a state-of-the-art single cylinder diesel research engine will be discussed. The major interest has been on engine emissions (NOx, PM, HC, CO, noise) compared to conventional diesel fuel.

Recently, a consistent mixing model for the two-way coupling of a CFD code and a zero-dimensional multi-zone code was developed. This work allowed for building an interactively coupled CFD-multi-zone approach that can be used to model HCCI combustion. In this study, the interactively coupled CFD-multi-zone approach is applied to PCCI combustion in a 1.9l FIAT GM Diesel engine. The physical domain in the CFD code is subdivided into multiple zones based on one phase variable (fuel mixture fraction). The fuel mixture fraction is the dominant quantity for the description of nonpremixed combustion. Each zone in the CFD code is represented by a corresponding zone in the zero-dimensional multi-zone code. The zero-dimensional multi-zone code solves the chemistry for each zone, and the heat release is fed back into the CFD code. The thermodynamic state of each zone, and thereby the phase variable, changes in time due to mixing and source terms (e.g., vaporization of fuel, wall heat transfer).

Subject of this work is the recently introduced extended Representative Interactive Flamelet (RIF) model for multiple injections. First, the two-dimensional laminar flamelet equations, which can describe the transfer of heat and mass between two-interacting mixture fields, are presented. This is followed by a description of the various mixture fraction and mixture fraction variance equations that are required for the RIF model extension accounting for multiple injection events. Finally, the modeling strategy for multiple injection events is described: Different phases of combustion and interaction between the mixture fields resulting from different injections are identified. Based on this, the extension of the RIF model to describe any number of injections is explained. Simulation results using the extended RIF model are compared against experimental data for a Common-Rail DI Diesel engine that was operated with three injection pulses.