Refine Your Search

Search Results

Viewing 1 to 2 of 2
Technical Paper

Thermally Durable Vanadium-SCR Catalysts for Diesel Applications

2013-04-08
2013-01-1063
The emission regulations for mobile applications will become stricter in Euro 4 - 6 levels and require the use of active aftertreatment methods (deNOx and DPF) in addition to passively operating diesel oxidation catalysts (DOC). Vanadium-SCR (V-Selective Catalytic Reduction) catalysts based on stabilized TiO₂-WO₃ raw materials and tailored preparation methods were first evaluated by the laboratory experiments. Conventional V-SCR catalysts were durable up to about 600°C but the developed catalyst stand hydrothermal ageing up to 700°C without losses of activity. Simultaneously, the performance at 250 - 450°C was about the same as with the traditional V-SCR catalyst and the SCR selectivity at 450 - 600°C was high with a low NH₃ oxidation tendency. Coated V₂O₅/TiO₂-WO₃ catalysts (ceramic and metallic substrates) were evaluated with a 4.9 L engine by engine bench experiments.
Technical Paper

Design of Durable Vanadium - SCR Catalyst Systems for Heavy - Duty Diesel Applications

2013-01-09
2013-26-0049
The emission regulations for mobile applications become stricter in Euro-IV to Euro-VI levels. Carbon monoxide and hydrocarbon can be removed by efficient Diesel Oxidation Catalysts (DOC) but Particulate Matter (PM) and NOx are more demanding requiring the use of active methods (urea-SCR and DPF) which will be world-wide implemented in the 2010's. Durable, coated V-SCR catalysts are based on stabilized raw materials and tailored preparation methods. Coated V2O5/TiO2-WO3 catalysts (ceramic 300/400 cpsi and metallic 500/600 cpsi) were evaluated by laboratory and engine bench experiments. Traditional V-SCR catalysts are durable up to about 600°C and have a high efficiency at 300°C-500°C. SCR activities were tailored to be higher also at 200°C-300°C or 500°C-600°C. The use of thermal stabilizers or the vanadium loading variation enabled the changes in operation window and stability.
X