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The environmental performance of automobiles and automobile engines in particular is the foremost issue in the automotive industry today. In addition, engine durability performance is an essential aspect of engine oil performance. Four-cycle motorcycle engine oils formulated with dialkyl phosphate, a sulfur-free additive developed as an alternative to ZDDP, provide excellent environmental and durability performance in terms of longer drain intervals, cleanliness and low corrosion properties.

With environmental issues at the forefront of the automotive industries, there is a clear need to improve the fuel economy and longer drain performance of four-cycle motorcycle engine oils. Evaluation of oil consumption in actual engines was used to clarify an optimal volatility for engine oils, and the feasibility of using zinc dialkyl phosphate, a sulfur-free additive, as an alternative to ZDTP for improved of fuel economy performance was studied. Engine oils with optimized additives demonstrated excellent friction characteristics and wet clutch performance.

The authors have spent considerable time studying the sulfur-free additive ZP as a means to improve the environmental properties of engine oils. ZP is an alternative compound to ZDDP, which has been a key engine oil additive for over 50 years. The ZP molecule contains oxygen in place of the sulfur found in ZDDP. In our past studies, various engine tests confirmed that ZP-blend engine oils outperform ZDDP-blend oils in terms of long-life and fuel-saving properties. Moreover, by using ZP, levels of sulfur can be reduced without sacrificing the oils' primary performance characteristics, so there less of an adverse effect on emission control systems, and lower levels of vehicle emissions can be achieved. We conducted field tests involving dozens of vehicles to verify the fuel economy retention and long-life performance of ZP oils. We report the results in this paper.

The deterioration of the friction reducing properties of engine oils containing molybdenum dithiocarbamates (MoDTCs) in service was studied. A quantitative analysis of MoDTCs and zinc dithiophosphates (ZDTPs) remaining in aged oils revealed that ZDTPs were consumed faster than MoDTCs. The consumption rate of ZDTPs was slow in the presence of MoDTCs and peroxide-decomposing antioxidants. The frictional properties of aged oils were evaluated with a reciprocating friction tester (SRV tester). The friction coefficient measured with the SRV tester was correlated to the properties of the aged oils, such as the TAN increase, TBN, and concentration of remaining ZDTPs.

Fuel efficient SAE 5W-20 automotive gasoline engine oils with molybdenum dithiocarbamates (MoDTCs) type friction modifiers were developed. The additive formulations were optimized with a motor-driven valve train friction test. The valve train friction was measured for both new oils and used oils, which had been prepared in a fired operation with bench engines, in order to evaluate the durability of the fuel efficiency. The combinations of MoDTCs, zinc dithiophosphates (ZnDTPs) and calcium salicylate type metallic detergents were found to be effective in reducing valve train friction and in improving its durability. From the results obtained, two oils, which had different ZnDTP formulations, were manufactured for evaluating field test performance. The SAE viscosity grade of the two oils was set at 5W-20 out of consideration of the reduction of hydrodynamic friction. Field test performance was evaluated with vehicles used for commuting in the Yokohama area.