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Thermodynamic characteristics of premixed compression ignition combustions were clarified quantitatively by heat balance estimation. Heat balance was calculated from temperature, mole fractions of intake and exhaust gases, mass and properties of fuels. Heat balance estimation was conducted for three types of combustion; a conventional diesel combustion, a homogeneous charge compression ignition (HCCI) combustion; fuel is provided and mixed with air in an intake pipe in this case, and an extremely early injection type PREmixed lean DIesel Combustion (PREDIC). The results show that EGR should be applied for premixed compression ignition combustion to complete combustion at lower load conditions and to control ignition timing at higher load conditions. With an application of EGR, both HCCI and PREDIC showed low heat loss characteristics at lower load conditions up to 1/2 load.

The effects of fuel injection timing on fuel-air mixture formation, combustion and emissions for a PREmixed lean DIesel Combustion (PREDIC) engine has been studied numerically by the KIVA II modeling package. The software was modified with an improved autoignition and combustion submodel, which describes the formation of combustible or ignitable fuel-air mixtures by turbulent mixing, and describes four chemical reactions, including low-temperature oxidation. The results indicate that the present computational model reproduces major features of two-stage autoignition and experimentally observed trends in NO and unburned fuel emissions. The relationships among in-cylinder distributions of fuel sprays, fuel-air equivalence ratio, temperature and mass fractions of NO and unburned fuel were demonstrated by graphically imaged results. A method of fuel-air mixture characterization has been introduced and used to analyze the numerical results.

Previous research in our laboratory has shown that NOx emissions can be sharply reduced by PREDIC (PRE-mixed lean DIesel Combustion), in which fuel is injected very early in the compression process. However some points of concern remained unsolved, such as a large increase in THC and CO, higher fuel consumption, and an operating region narrowly limited to partial loads, compared to conventional diesel operation. In this paper, the causes of PREDIC's problem areas were analyzed through engine performance tests and combustion observation with a single cylinder engine, through fuel spray observation with a high-pressure vessel, and through numerical modeling. Subsequently, measurable improvements were achieved on the basis of these analyses. As a result, the ignition and combustion processes were clarified in terms of PREDIC fuel-air mixture formation. Thus, THC and CO emissions could be decreased by adopting a pintle type injection nozzle, or a reduced top-land-crevice piston.

Previous research in our laboratory has shown that NOx emissions can be sharply reduced by PREDIC (PRE-mixed lean DIesel Combustion), in which fuel is injected very early in the compression process. However some problems still remain, such as higher fuel consumption, a lack of ignition timing control, and a large increase in THC and CO, compared to conventional diesel combustion. Appropriate mixture formation is necessary to solve these problems. In this paper, the influence of mixture formation on PREDIC was investigated. It was found that the pintle type injection nozzle was shown to be suitable for PREDIC, because it produced a comparatively uniform mixture in the combustion chamber and avoided collision of the fuel spray with the cylinder liner. Modeling by the KIVA-II software package was carried out to improve our understanding of the mixture formation process.

Experiments on a large number of soluble fuel additives were systematically conducted for diesel soot reduction. It was found that Ca and Ba were the most effective soot suppressors. The main determinants of soot reduction were: the metal mol-content of the fuel, the excess air factor, and the gas turbulence in the combustion chamber. The soot reduction ratio was expressed by an exponential function of the metal mol-content in the fuel, depending on the metal but independent of the metal compound. A rise in excess air factor or gas turbulence increased the value of a coefficient in the function, resulting in larger reductions in soot with the fuel additives. High-speed soot sampling from the cylinder showed that with the metal additive, the soot concentration in the combustion chamber was substantially reduced during the whole period of combustion. It is thought that the additive acts as a catalyst not only to improve soot oxidation but also to suppress soot formation.