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Technical Paper

Dynamic Monitoring of Differentiated Hydrocarbons in Direct Engine Exhaust: A Versatile Tool in Engine Development

1996-02-01
960063
In the compression and combustion strokes different individual hydrocarbons are generated through a complex reaction chemistry and can be monitored by a rapid V&F multicomponent gas analyzer system. They give detailed information on the physical properties of an engine. Through all different reaction sequences of the combustion, surface quenching reactions leave a characteristic pattern of hydrocarbons in the exhaust gas. Toluene and xylene, for example, represent direct monitors for unburnt fuel, alkenes and alkines show thorough fuel decomposition, allowing a rapid combustion when the spark is ignited, whereas aldehydes indicate autoignition processes. Ratios of hydrocarbon concentrations describe engine parameters like fuel/air mixing properties, EGR characteristics, autoignition processes, and engine oil combustion. So an optimized engine performance can be set by the hydrocarbon pattern measured in the direct exhaust gas.
Technical Paper

SIMS 500 - Rapid Low Energy Secondary Ion Mass Spectrometer for In-Line Analysis of Gaseous Compounds - Technology and Applications in Automotive Emission Testing

1993-11-01
932017
A new multichannel gas analyzer based on ion - neutral interaction principles is introduced. This gas phase secondary ion mass spectrometer using several well defined energy levels for the ionization process quantitatively analyzes gas mixtures without the use of presetection techniques. A high sensitivity for many compounds together with high cycle rates allows dynamic studies of gaseous emission in the low and sub ppm range. Transient studies of inorganic compounds like NO, NH3, H2S, COS and SO2 in catalytic converter systems and differentiated Hydrocarbon analyses of C1 to C8 prove the versatility of the instrument.
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