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In this work, the effects of ozone, hydrogen, carbon monoxide, and exhaust gas recirculation (EGR) addition to Haltermann gasoline combustion were investigated. For these additives, laminar and turbulent flame speeds were experimentally determined using spherically propagating premixed flames in a constant volume combustion vessel. Two initial mixture pressures of Po = 1 and 5 bar, two initial mixture temperatures of 358 and 373 K and a range of equivalence ratios (Ф) from 0.5 to 1 were investigated. The additives were added as single, binary and ternary mixtures to Haltermann gasoline over a wide range of concentrations. For the stoichiometric mixture, the addition of 10% H2, 5% CO and 1000 ppm O3 shows remarkable enhancement (80%) in SL0compared to neat Haltermann gasoline. In addition, for this same blend, increasing the mixture initial temperature and pressure results in a significant increase in SL0compared to the neat gasoline.

The auto-ignition of liquid fuel and lubricant oil droplets is considered as one of the possible sources of pre-ignition. Researchers are continually finding new ways to form advanced lubricant oil by changing its composition and varying different oil additives to prevent the occurrence of this event. This study investigates additives for lubricants to suppress its auto-ignition tendency. Three sets of mixtures were prepared. The first set of mixtures were prepared by adding different alcohols namely ethanol, and methanol to the commercial lubricant oil (SAE 15W-40) in ratio of 1 - 5 % by vol The second set of mixtures were prepared by mixing SAE 15W-40 with aforementioned alcohols (1 % vol.) and H2O (1 % vol.). Lastly, the third set of mixtures were prepared by adding toluene to SAE 15W-40 in (1 % - 5% by vol.). Two experimental setups were used in the current work.

Numerous studies have attributed pre-ignition events in turbocharged spark ignited engines to the auto-ignition of lubricant oil-fuel mixture droplets. These droplets result from the interaction of the directly injected fuel spray on the lubricant oil film on the cylinder walls, causing fuel splashing to pull oil off the walls, forming droplets. The dilution of the oil by the fuel also changes lubricant oil droplet properties. Therefore, it is important to understand lubricating oils, with and without fuel dilution, as a possible ignition source in pre-ignition and super knock events. In this work, a constant volume (4 L) combustion chamber (CVCC) that allows the introduction of a single droplet of lubricating oil has been built. It is capable of operation at elevated pressures and temperatures. To simulate the droplet-induced pre-ignition event, a droplet injection system was incorporated into the vessel.

Numerical simulations were conducted to systematically assess the effects of different spray models on the ignition delay predictions and compared with experimental measurements obtained at the KAUST ignition quality tester (IQT) facility. The influence of physical properties and chemical kinetics over the ignition delay time is also investigated. The IQT experiments provided the pressure traces as the main observables, which are not sufficient to obtain a detailed understanding of physical (breakup, evaporation) and chemical (reactivity) processes associated with auto-ignition. A three-dimensional computational fluid dynamics (CFD) code, CONVERGE™, was used to capture the detailed fluid/spray dynamics and chemical characteristics within the IQT configuration. The Reynolds-averaged Navier-Stokes (RANS) turbulence with multi-zone chemistry sub-models was adopted with a reduced chemical kinetic mechanism for n-heptane and iso-octane.