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Co-Optimization of Fuels and Engines initiative (Co-Optima) of the U.S Department of Energy started investigations on several candidates of biofuels and blends for internal combustion engines. At this stage, only a few biomass-derived fuel blendstocks (including ethanol) for advanced spark-ignition engines have been selected using enhanced screening criteria, which included boiling point, toxicity, research octane number, octane sensitivity, and economical distribution system, etc. Ethanol, of which this paper is focused on, is also an important fuel because of its high-octane number which in turn promotes advance ignition timing and higher thermal efficiencies in reciprocating engines. Measurements of laminar burning velocity (LBV) is a key metric to understand fuel performance and applicability in engines. Furthermore, in order to quantify more complicated, and practical, burning regimes such as turbulent combustion much of the underlying theory requires knowledge of LBV.

Laminar burning velocity (LBV) measurements are reported for promising high-performance fuels selected as drop-in transportation fuels to automotive grade gasoline as part of the United States Department of Energy’s Co-Optimization of Fuels and Engines Initiative (Co-Optima). LBV measurements were conducted for ethanol, methyl acetate, and 2-methylfuran with synthetic air (79.0 % N2 and 21.0 % O2 by volume) within a constant-volume spherical combustion rig. Mixture initial temperature was fixed at 428±4 K, with the corresponding initial pressure of 1.00±0.02 atm. Current LBV of ethanol is in good agreement with literature data. LBV of ethanol and 2-methylfuran showed similar values over the range of equivalence ratios, while methyl acetate exhibited an LBV significantly lower over the range of tested equivalence ratios. The maximum laminar burning velocity occurred at slightly richer equivalence ratio from the stoichiometric value for all fuels tested.

The 2,4-dimethyl-3-pentanone (DIPK) is a promising biofuel candidate for automotive applications that is produced by the endophytic fungal conversion process which can be optimized for widespread utilization. There are some studies in the literature on combustion properties of DIPK, such as ignition delay times and laminar burning velocity (LBV) measurements. However, most studies are conducted one atmospheric (atm) pressure which are far away from the high-pressure conditions present inside reciprocating engines. Therefore, we present LBV measurements at high pressures up to 10 atm for this fuel using a spherical flame speed facility. It is known that the flame in a constant volume chamber develops cellular structure (hydrodynamic instability) as the initial pressure increases because of the reduction in flame thickness. In addition, the diffusional-thermal instability prevents experiments for rich mixtures because of the reduction of Lewis number (Le).