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Technical Paper

Modeling and Analysis of the Hydrogen Production via Steam Reforming of Ethanol, Methanol, and Methane Fuels

2024-04-09
2024-01-2179
The global transition to alternative power sources, particularly fuel cells, hinges on the cost-effective production and distribution of hydrogen fuel. While green hydrogen produced through water electrolysis using renewable energy sources holds immense promise, it currently falls short of meeting the burgeoning demand for hydrogen. To address this challenge, alternative methods, such as steam reforming and partial oxidation of hydrocarbon fuels with integrated carbon capture, are poised to bridge the gap between supply and demand in the near to midterm. Steam reforming of methane is a well-established technology with a proven track record in the chemical industry, serving as a dependable source of hydrogen feedstock for decades. However, to meet the demand for efficient hydrogen storage, handling, and onboard reforming, researchers are increasingly exploring liquid hydrocarbon fuels at room temperature, such as methanol and ethanol.
Technical Paper

Modeling of Vent Gas Composition during Battery Thermal Runaway

2024-04-09
2024-01-2199
The growing global adoption of electric vehicles (EVs) emphasizes the pressing need for a comprehensive understanding of thermal runaway in lithium-ion batteries. Prevention of the onset of thermal runaway and its subsequent propagation throughout the entire battery pack is one of the pressing challenges of lithium-ion batteries. In addition to generating excess heat, thermal runaway of batteries also releases hazardous flammable gases, posing risks of external combustion and fires. Most existing thermal runaway models in literature primarily focus on predicting heat release or the total amount of vent gas. In this study, we present a model capable of predicting both heat release and the transient composition of emitted gases, including CO, H2, CO2, and hydrocarbons, during thermal runaway events. We calibrated the model using experimental data obtained from an 18650 cell from the literature, ensuring the accuracy of reaction parameters.
Journal Article

Strategies for Reduced Engine-Out HC, CO, and NOx Emissions in Diesel-Natural Gas and POMDME-Natural Gas Dual-Fuel Engine

2022-03-29
2022-01-0460
Dual-fuel engines employ precisely metered amounts of a high reactivity fuel (HRF) such as diesel at high injection pressures to burn a low reactivity fuel (LRF) such as natural gas, which is typically fumigated into the intake manifold. Dual fuel engines have demonstrated the ability to achieve extremely low engine-out oxides of nitrogen (NOx) emissions compared to conventional diesel combustion at the expense of unburned hydrocarbon (HC) and carbon monoxide (CO) emissions. At low engine loads, due to low in-cylinder temperatures, oxidation of HC and CO is very challenging. This results in both compromised combustion and fuel conversion efficiencies.
Technical Paper

Experimental Study of Spark-Ignition Combustion Using the Anode Off-Gas from a Solid Oxide Fuel Cell

2020-04-14
2020-01-0351
Hybridizing Solid Oxide Fuel Cells (SOFCs) with internal combustion engines is an attractive solution for power generation at high electrical conversion efficiency while emitting significantly reduced emissions than conventional fossil fueled plants. The gas that exits the anode of an SOFC operating on natural gas is a mixture of H2, CO, CO2, and H2O vapor, which are the products of the fuel reforming and the electrochemical process in the stack. In this study, experiments were conducted on a single-cylinder, spark-ignited Cooperative Fuel Research Engine using the anode off-gas as the fuel, at compression ratio of 11:1 and 13:1, engine speed of 1200 rev/min and intake pressure of 75 kPa, to investigate the combustion characteristics and emissions formation. A comparison was drawn with combustion with Compressed Natural Gas (CNG) at the same engine operating conditions.
Journal Article

The Effects of Thick Thermal Barrier Coatings on Low-Temperature Combustion

2020-04-14
2020-01-0275
An experimental study was conducted on a Ricardo Hydra single-cylinder light-duty diesel research engine. Start of Injection (SOI) timing sweeps from -350 deg aTDC to -210 deg aTDC were performed on a total number of five pistons including two baseline metal pistons and three coated pistons to investigate the effects of thick thermal barrier coatings (TBCs) on the efficiency and emissions of low-temperature combustion (LTC). A fuel with a high latent heat of vaporization, wet ethanol, was chosen to eliminate the undesired effects of thick TBCs on volumetric efficiency. Additionally, the higher surface temperatures of the TBCs can be used to help vaporize the high heat of vaporization fuel and avoid excessive wall wetting. A specialized injector with a 60° included angle was used to target the fuel spray at the surface of the coated piston.
Technical Paper

Effects of Single versus Two-Stage Heat Release on the Load Limits of HCCI Using Primary Reference Fuels

2019-04-02
2019-01-0950
Homogeneous Charge Compression Ignition (HCCI) enables combustion with high efficiency and low emissions. Control over the combustion process and its narrow operating range are still the biggest challenges associated with HCCI. To expand the operable load ranges of HCCI, this paper explores the effects of single versus two-stage ignition fuels by studying the Primary Reference Fuels (PRF) in a variable compression ratio Cooperative Fuel Research (CFR) engine. The PRF fuels, iso-octane and n-heptane, are blended together at various concentrations to create fuel blends with different autoignition characteristics. Experiments were conducted using these PRF blends to explore the extent to which the load range can be extended with two-stage ignition fuels at various compression ratios and intake temperatures. The reactivity of the PRF blends increases with the fraction of n-heptane and so does the amount of low temperature heat release (LTHR).
Technical Paper

Understanding HCCI Combustion in a Free Piston Engine with a Multi-Zone, Control-Mass Model with Thermal Stratification and Chemical Kinetics

2019-04-02
2019-01-0958
Homogeneous Charge Compression Ignition (HCCI) is a combustion concept with the potential for future clean and efficient automotive powertrains. In HCCI, the thermal stratification has been proven to play an important role in dictating the combustion process, mainly caused by heat transfer to the wall during compression. In this study, a multi-zone, control-mass model with thermal stratification and chemical kinetics was developed to simulate HCCI combustion. In this kind of model, the initial conditions and the zonal heat transfer fraction distribution are critical for the modeling accuracy and usually require case-by-case tuning. Instead, in this study, the Thermal Stratification Analysis (TSA) methodology is used to generate the zonal heat transfer fraction distribution from experimental HCCI data collected on a fired, metal engine.
Journal Article

Efficiency and Emissions Characteristics of an HCCI Engine Fueled by Primary Reference Fuels

2018-04-03
2018-01-1255
This article investigates the effects of various primary reference fuel (PRF) blends, compression ratios, and intake temperatures on the thermodynamics and performance of homogeneous charge compression ignition (HCCI) combustion in a Cooperative Fuels Research (CFR) engine. Combustion phasing was kept constant at a CA50 phasing of 5° after top dead center (aTDC) and the equivalence ratio was kept constant at 0.3. Meanwhile, the compression ratio varied from 8:1 to 15:1 as the PRF blends ranged from pure n-heptane to nearly pure isooctane. The intake temperature was used to match CA50 phasing. In addition to the experimental results, a GT-Power model was constructed to simulate the experimental engine and the model was validated against the experimental data. The GT-Power model and simulation results were used to help analyze the energy flows and thermodynamic conditions tested in the experiment.
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