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The effects of high boiling point fuel additives on deposits were investigated in a commercial turbocharged direct injection gasoline engine. It is known that high boiling point substances have a negative effect on deposits. The distillation end points of blended fuels containing these additives may be approximately 15°C higher than the base fuel (end point: 175°C). Three additives with boiling points between 190 and 196°C were examined: 4-tert-Butyltoluene (TBT), N-Methyl Aniline (NMA), and 2-Methyl-1,5-pentanediamine (MPD). Aromatics and anilines, which may be added to gasoline to increase its octane number, might have a negative effect on deposits. TBT has a benzene ring. NMA has a benzene ring and an amino group. MPD, which has no benzene ring and two amino groups, was selected for comparison with the former two additives.

Methanol steam reforming, which is an endothermic reaction, needs some heating. Both methanol conversion ratio and carbon monoxide (CO) concentration increase when temperature is elevated. As CO poisons a typical polymer electrolyte of a fuel cell, the relationship between methanol conversion ratio and CO concentration is a trade-off one. It was found from preliminary researches that the reforming reaction speed is controlled by heat transfer rate at large methanol flow rate, where methanol conversion ratio becomes lower and CO concentration becomes higher. Therefore it is necessary to develop a new methanol reforming concept that provides stable combustion for heating and enhanced heat transfer for improving the trade-off relationship and making a compact reformer. Reforming catalyst using metal honeycomb support and a new catalytic combustion were applied to a new concept plate type methanol steam reformer, which is used in a fuel cell of 3 kW-class electric generation.