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A chemical kinetics and computational fluid-dynamics (CFD) analysis was performed to evaluate the combustion of syngas derived from biomass and coke-oven solid feedstock in a micro-pilot ignited supercharged dual-fuel engine under lean conditions. For this analysis, a reduced syngas chemical kinetics mechanism was constructed and validated by comparing the ignition delay and laminar flame speed data with those obtained from experiments and other detail chemical kinetics mechanisms available in the literature. The reaction sensitivity analysis was conducted for ignition delay at elevated pressures in order to identify important chemical reactions that govern the combustion process. We have confirmed the statements of other authors that HO2+OH=H2O+O2, H2O2+M=OH+OH+M and H2O2+H=H2+HO2 reactions showed very high sensitivity during high-pressure ignition delay times and had considerable uncertainty.

Replacing the conventional fossil fuel totally or partially with alcohols or ethers in spark-ignition (SI) engine is a promising way to reduce pollutant emissions. A large number of studies on alcohol-containing blends in SI engines could be found in the literature. Nonetheless, investigations of ether-containing blends are by far much less numerous, especially for modern boosted engines. Blending with ether compounds might change the burning rate at high pressure, which consequently changes the anti-knock properties of these fuels and leads to a deterioration in the vehicle drivability. This work reports experiments carried out in two one-cylinder engines: one is a naturally aspirated, variable compression ratio engine, and the other is a strongly charged optical engine. Three fuels with different RON and MON numbers were tested: Iso-octane, a blend Ethyl Tert Butyl Ether (ETBE) with a primary reference fuel, and a commercial gasoline fuel containing 5% by volume of ethanol (E05).