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To minimize nitrogen oxide (NOx) as well as carbon monoxide (CO) and hydrocarbon (HC) emissions to fulfil the new European real driving emissions (RDE) legislation, the LNT operation strategy - especially for DeNOx events (rich mode) - has to be optimized. On one hand the DeNOx purges should be long enough to fully regenerate the lean NOx trap, on the other hand the purges should be as short as possible to reduce the fuel consumption penalty from rich mode. Fundamental experiments have been conducted on a synthetic-gas-test-bench, purposely designed to test LNT catalysts. This methodology allowed to remove NOx from the gasfeed after the lean storage phase. The actually reduced amount of NOx could be easily calculated from the NOx storage before a regeneration event minus the NOx that was desorbed during the DeNOx event and afterwards thermally desorbed NOx.