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The use of diesel particulate filter [DPF] has become a standard in modern diesel engine after treatment technology. However pressure drop develops across the filter as PM accumulates and this requires quick periodic burn-out without incurring thermal runaway temperatures that could compromise DPF integrity during operation. Adequate understanding of soot oxidation is needed for design and manufacture of efficient filter traps for the engine system. In this study, we have examined the impact of blending biodiesel on oxidation of PM generated from a high speed direct injection [HSDI] diesel engine, which was operated with 20% [B20] and 40% [B40] blends of two biodiesel fuels. The PM samples were collected from the engine exhaust using a Pall Tissuquartz filter, the oxidation characteristics of the samples were carried out using thermogravimetric analyzer [TGA]. The biodiesel oxidation data obtained from pure petrodiesel was compared against the fuel blends.