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Dimethyl ether (DME) attracts increasing attentions in recent years, because it can reduce the carbon monoxide (CO), unburned hydrocarbon (HC), and soot emissions for engines as the transportation fuel or the fuel additive. In this paper, a reduced DME oxidation mechanism is developed using the decoupling methodology. The rate constants of the fuel-related reactions are optimized using the non-dominated sorting genetic algorithm II (NSGA-II) to reproduce the ignition delay times in shock tubes and major species concentrations in jet-stirred reactors (JSR) over low-to-high temperatures. In NSGA-II, the range of the rate constants was considered to ensure the reliability of the optimized mechanism. Moreover, an improved objective function was proposed to maintain the faithfulness of the optimized mechanism to the original reaction mechanism, and a new method was presented to determine the optimal solution from the Pareto front.

The phenomenon of a thin liquid film separation and atomization at expanding corners during the spray/wall interaction is usually encountered in premixed charge compression ignition (PCCI) engines. However, detailed information about the film separation is very limited, especially under high injection pressure conditions. In this study, experimental study was conducted to investigate the effects of injection pressure and impingement distance on the evolutions of the impinging spray and the adhered film at simplified geometries with an expanding corner by employing a high-speed camera. In addition, an improved hybrid film separation and atomization model was developed, which includes the sub-models of film separation criterion, film separation mass ratio, and the film atomization model based on the Rayleigh-Taylor instability theory.