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On the way to a climate-neutral mobility, synthetic fuels with their potential of CO2-neutral production are currently in the focus of internal combustion research. In this study, the C1-fuels methanol (MeOH), dimethyl carbonate (DMC), and methyl formate (MeFo) are tested as pure fuel mixtures and as blend components for gasoline. The study was performed on a single-cylinder engine in two configurations, thermodynamic and optical. As pure C1-fuels, the previously investigated DMC/MeFo mixture is compared with a mixture of MeOH/MeFo. DMC is replaced by MeOH because of its benefits regarding laminar flame speed, ignition limits and production costs. MeOH/MeFo offers favorable particle number (PN) emissions at a cooling water temperature of 40 °C and in high load operating points. However, a slight increase of NOx emissions related to DMC/MeFo was observed. Both mixtures show no sensitivity in PN emissions for rich combustions. This was also verified with help of the optical engine.

In this study, a fully optically accessible single-cylinder research engine is the basis for the visualization and generation of extensive knowledge about the in-cylinder processes of mixture formation, ignition and combustion of oxygenated synthetic fuels. Previous measurements in an all-metal engine showed promising results by using a mixture of dimethyl carbonate and methyl formate as a fuel substitute in a DISI-engine. Lower THC and NOx emissions were observed along with a low PN-value, implying low-soot combustion. The flame luminosity transmitted via an optical piston was split in the optical path to simultaneously record the natural flame luminosity with an RGB high-speed camera. The second channel consisted of OH*-chemiluminescence recording, isolated by a bandpass filter via an intensified monochrome high-speed camera.

Improving efficiency and reducing emissions are the principal challenges in developing new generations of internal combustion engines. Different strategies such as downsizing or sophisticated after-treatment of exhaust gases are pursued. Another approach aims at optimizing the parameterization of the engine. Correct adjustments of ignition timings, waste gate position and other factors have significant influence on the combustion process. A multitude of application data is generated during the development process to predefine appropriate settings for most situations. Improvements in regards to the application effort and the quality of the settings can be achieved by measuring the combustion process and optimizing the parametrization in a closed loop. However, cylinder pressure sensors that are used during the development process are too expensive for series applications.