Search Results

We propose a reduced order model (ROM) for LFP/graphite cells derived from the electrochemical thermal principles that considers degradation effects and validated against experimental data obtained from a large format pouch type LFP/graphite cell whose nominal capacity is 20Ah. The characteristics of the two-phase transition and path dependence were taken into account in the ROM using a shrinking-core model with a moving interface that presents lithium rich and deficient phase. Different currents (0.1/1/3/4C) were applied to fresh cells at different ambient temperatures (25/35/45°C). Comparison between simulated results of the ROM and the collected experimental data shows a good match. The path dependence was also analyzed experimentally. For degradation model, side reaction is treated as the predominant cause of degradation of cells, which are affected by the operating conditions, such as temperature and SOC cycling range.