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The thermal efficiency of spark-ignition engines can be enhanced by increasing the rate of exhaust gas recirculation (EGR) such that the low temperature combustion regime could be achieved. However, there is an upper limit on the amount of EGR rate, beyond which flame speed becomes slow and unstable, and local quenching starts to hurt the combustion stability, efficiency, and emission. To resolve this issue, the concept of dedicated EGR has been proposed previously to be an effective way to enhance flame propagation under lean burn condition with even higher levels of EGR with reformate hydrogen and carbon monoxide. In this study, the effects of thermochemical fuel reforming on the reformate composition under rich conditions (1.0 < ϕ < 2.0) have been studied using detailed chemistry for iso-octane, as the representative component for gasoline.