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The investigation has been divided into two parts. In part one, numerical investigations of the effect of humid air with different levels of humidity on gaseous emissions of a non-premixed combustion have been investigated. This part of the investigation was a feasibility study, focused on how different levels of humidity in the intake air affects the exhaust NO emission. Part two of the investigation was verification of the numerical results with a naturally aspirated engine with natural gas as the fuel. Here, we also investigated the impact of humid air intake on engine’s particulate matter (PM) emission. For the numerical investigations, the non-premixed combustion in a single cylinder was simulated using the presumed probability density function combustion model. Simulations were performed for dry as well as humid intake air for 0%, 15%, and 30% relative humidity (RH).