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Stricter regulatory standards are continuously adopted worldwide to control heavy duty emissions, and at the same time, fuel economy requirements have significantly lowered exhaust temperatures. The net result is a significant increase in Precious Group Metal (PGM) usage with current Diesel Oxidation Catalyst (DOC) technology. Therefore, the design and development of synergized precious metal (SPGM) in which ultra-low PGM is synergized with mixed metal oxide (MMO) to achieve highly beneficial emission performance improvement, is necessary. The presence of MMO in SPGM is responsible for NO oxidation to NO2 which is critical for the passive regeneration of the downstream filter and SCR function. This paper presents an initial study outlining the development of MMOs for application in modern DOCs and addresses some specific challenges underlying this application. Lab and flow reactor data in this study demonstrated SPGM DOCs thermal resistance and sulfur poisoning resistance.