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The natural refrigerant, R744 (CO2), remains a viable solution to replace the high GWP refrigerant R134a which is to be phased out in light-duty vehicles in EU and US market. In this study, thermodynamic analysis is performed on a R744 parallel compression system to evaluate its potential in automotive climate control. The model adopts a correlation of isentropic efficiency as a function of compression ratio based on a prototype R744 MAC compressor and accounts for the operating limits defined in the latest DIN specifications. Optimization is run over typical MAC operating conditions which covers both transcritical and subcritical domain. Comparing to the conventional single compression cycle, effectiveness of parallel compression is found most pronounced in low evaporating temperature and high ambient conditions, with up to 21% increase in COP and 5.3 bar reduction in discharge pressure observed over the considered parametric range.

CO2 is an alternative to replace the conventional refrigerant (R134a) for the air-conditioning system, due to the high Global Warming Potential (GWP) of R134a. There are concerns with the use of CO2 as a refrigerant due to health risks associated with exposure to CO2, if the concentration of CO2 is over the acceptable threshold. For applications with CO2 as the refrigerant, the risk of CO2 exposure is increased due to the possibility of CO2 leakage into the cabin through the duct system; this CO2 is in addition to the CO2 generated from the respiration of the occupants. The initiation of the leak could be due to a crash event or a malfunction of the refrigerant system. In an automobile, where the interior cabin is a closed volume (with minimal venting), the increase in concentration can be detrimental to the customer but is hard to detect.