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The ignition delay time of toluene reference fuels composed of iso-Octane, n-heptane and toluene was studied in a shock tube under the conditions of medium to high temperature ranges, different pressures (10-20 bar), and various equivalence ratios (0.5,1.0,1.5 and 2) by reflected waves.Three different ternary blends, TRF2 (42.8% iso-Octane/13.7% n-heptane/43.5% toluene), TRF3 (65% iso-Octane/10% n-heptane/25% toluene) and TRF4 (87.2% iso-Octane/6.3% n-heptane/6.5% toluene), with the same Research Octane Number of 95 (RON=95) were constructed. The experimental results showed that there was an obvious negative correlation between the ignition delay time of the toluene reference fuels and the pressure, temperature and equivalence ratio; and, a minimal discrepancy of TRF2, TRF3, and TRF4 was measured at pressures of 10 and 20 bar in a stoichiometric ratio. A detailed chemical mechanism was established to research the surrogate combustion properties.