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With the upcoming Euro 6c emission regulations, the performance of Diesel exhaust lines needs to be improved to meet NOX and soot emission targets. A promising exhaust line architecture to reach these requirements is the association of a Diesel Oxidation Catalyst (DOC), a Selective Catalytic Reduction coated on a particulate filter (SCR-F) and a Selective Catalytic Reduction (SCR) catalyst. To develop this system, the car manufacturers have to face several challenges. One of the first is the design of the exhaust line volumes, which has a strong impact on the light-off temperatures of the catalysts and so on system performance. Then, urea injection has to be optimized with an adapted control system to maximize NOx reduction while keeping low tailpipe ammonia emission. Moreover, performance degradation of catalysts due to harsh exhaust conditions during vehicle life time have to be detected by OBD system.