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Technical Paper

Oxidative Deterioration Properties of FAME-Blended Diesel Fuel

2018-04-03
2018-01-0924
The correlation between newly approved EN 15751 and the internal diesel injector deposits (IDID) due to fuel oxidative deterioration has not been made clear. In the present research, the Rancimat method was slightly modified to research the relationship between fuel oxidative deterioration and the deterioration products generated from the fuel. After heating fuel at 120 to 150°C for a set period, insoluble deterioration products (IDID-like substances) were generated and their weights were measured. At the same time, the shifts of the conductivity in trap water were analyzed from a new perspective, and its relationship with the deterioration products was investigated. At 120°C and 130°C, conductivity rising rates after the inflection point (this set of data represents the rate of organic acid generation in the fuel, and we named “Oxidation rate”) exhibited a strong correlation with the quantity of deterioration products.
Journal Article

Development of Electropolishing-Based Corrosion Resistance Technique for Ferritic Stainless Steel

2016-04-05
2016-01-0354
1 One issue raised by the use of austenitic stainless steels in commercial vehicles is the increase in material costs. To reduce those material costs, a nitric acid electropolishing treatment was applied to SUS436L (18 Cr - 1.5 Mo - 0.4 Nb) and corrosion tests were conducted to compare its corrosion resistance to that of SUS316L(16 Cr - 12 Ni - 2 Mo). Compared to SUS316L, SUS436L subjected to nitric acid electropolishing indicated superior corrosion resistance. In addition, XPS and TEM analyses showed that while the SUS436L passivation film layer contained approximately twice as much chromium, its thickness was also generally reduced by approximately half, to 2 nm. These results suggest that electropolishing with nitric acid, which is highly oxidative, formed a fine passivation film.
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