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Impingement of spray against the cylinder wall or piston bowl is an unavoidable physical process in homogeneous charge compression ignition (HCCI) and premixed charge compression ignition (PCCI) engines using early injection strategy. It directly affects fuel-air mixture formation, combustion and exhaust emission. In addition, the alcohol fuels such as methanol, ethanol and n-butanol are regarded as hopeful alternative fuels as well as fuel additive for HCCI and PCCI diesel engines to improve the emission level. The better understanding for the effect of alcohol-diesel blending fuel on the spray-wall impingement process is helpful for the improvement of HCCI and PCCI diesel engines. In this paper, the effects of three different alcohol-diesel blending fuels (methanol, ethanol and n-butanol) on the spray-wall impingement process were studied. Numerical investigation was performed in AVL FIRE code.