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In vehicles with urea-SCR system, normal operation of the urea-SCR system and engine will be influenced if there are deposits appearing on exhaust pipe wall. In this paper, a commercial vehicle is employed to study the influence factors of deposits through the vehicle road test. The results show that, urea injection rate, temperature and flow field have impacts on the formation of deposits. When decreasing the urea injection rate of calibration status by 20%, the deposit yield would reduce by 32%. If the ambient temperature decreased from 36 °C to 26 °C, the deposit yield would increase by 95%. After optimizing the exhaust pipe downstream of the urea injector by removing the step surface, only a few flow marks of urea droplets are observed on the pipe wall, and no lumps of deposits existing.