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The cluster of excellence “Tailor-Made Fuels from Biomass” (TMFB) at RWTH Aachen University seeks to identify and investigate new potential biofuels and their production routes. To ensure a safe handling in common-rail systems the lubricity of future biofuels is part of the investigations. To further deepen the understanding of the behaviour of such fluids in the regime of boundary lubrication a group of twelve potential biofuels and systematically derived fluids was investigated by a modified version of the standardised High Frequency Reciprocating Rig test procedure for Diesel lubricity. Insufficient lubricity is observed for most biofuels whereas linear molecules with polar head groups provide good or very good lubrication. For all studied groups longer molecules provide better lubricities. The position of the functional group significantly influences the overall lubricity and impact of the carbon chain length.

In this paper compatibility studies of biofuel candidates and similar liquids with the elastomeric materials nitrile butadiene rubber and fluoroelastomer are presented. The results gained with defined reference elastomers are compared to results gained with the materials used in the technical application. For this purpose test specimens are prepared from fuel hoses and the material used for shaft seals of fuel pumps. The experimental results are subsequently used to evaluate prediction approaches based on the HSP- and QSPR-method. Finally a comparison of these two approaches is given.