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In a regulatory environment for spark ignition (SI) engines where the focus is continuously looking into improvements in fuel economy and reduction in noxious emissions, the challenges to achieve future requirements are utmost. To effectively reduce CO2 emissions on a well-to-wheel basis, future fuels enabling high efficiency SI engines will have to not only satisfy advanced engine requirements, i.e. high knock resistance, but also produce less CO2 emissions in the refinery. This paper describes how to characterize SI combustion's on-demand octane requirement with three different dual fuel configurations. Refinery naphtha was used for low octane component, and three oxygenates were used for high octane knock inhibiting component, such as, Methanol and Methyl tert-butyl ether (MTBE) and Ethyl tert-butyl ether (ETBE). Each low and high octane fuel was introduced via production gasoline direct injector (DI) and port fuel injector (PFI) in both configurations.