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China 6 emission legislation was finalized in 2018 and the full implementation nationwide is postponed to 2021 due to COVID-19. It is foreseen that the post China 6 legislation will have more stringent primary and secondary emission requirements including further reduction of nitrous oxide (N2O) emissions and likely to include limits on ammonia (NH3) emissions. This study investigated the secondary emissions (i.e. N2O and NH3) of a variety of China 6 production gasoline vehicles operating under the worldwide harmonized light vehicles test cycle (WLTC) and random test standardized aggressive (RTS 95) cycle. It was found that N2O emissions were less than 5 mg/km on all these vehicles, far below the current China 6 limit (20 mg/km), however NH3 emissions varied from 2 to 48 mg/km among the production vehicles. The mechanisms of N2O and NH3 formation and their correlation with primary emissions were also investigated.

The new emission regulations in Europe, EU 6 will promulgate more realistic driving conditions with more stringent HC, CO, NOx and particulate emissions. This legislation will also include the WLTP (Worldwide harmonized Light vehicles Test Procedure) cycle for CO2 measurements and a new requirement called “Real-Driving-Emissions” (RDE) as well. The RDE requirement is to ensure modern vehicles comply with the legislation under all conditions of normal driving. More robust aftertreatment solutions are needed to meet these new requirements. This work introduces an improved three-way catalyst (TWC) for gasoline engines for these new regulations. It is tested under static and dynamic conditions and on several engines and vehicles with various drive cycles. It offers better thermal stability combined with lower backpressure than former TWC generations.