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In this study, two oxygenated fuels consisting of butanol and diethyl ether (DEE), both possess same number of carbon, hydrogen and oxygen atom but difference functional group, were blended with the waste plastic pyrolysis oil to use in a 4-cylinder direct injection diesel engine without any engine modification. In addition, the effect of castor oil addition to such fuel blends was also investigated. Four tested fuels with same oxygen content were prepared for engine test, comprising DEE16 (84% waste plastic oil blended with 16% DEE), BU16 (84% waste plastic oil blended with 16% butanol), DEE11.5BIO5 (83.5% waste plastic oil blended with 11.5% DEE and 5% castor oil) and BU11.5BIO5 (83.5% waste plastic oil blended with 11.5% butanol and 5% castor oil). The results found that the DEE addition to waste plastic oil increased more HC and smoke emissions than the butanol addition at low engine operating condition.

Due to the emission benefits of the oxygen in the fuel molecule, the interest for the use of ethanol as fuel blend components in compression ignition engines has been increased. However the use of fuel blends with high percentage of ethanol can lead to poor fuel blend quality (e.g. fuel miscibility, cetane number, viscosity and lubricity). An approach which can be used to improve these properties is the addition of biodiesel forming ternary blends (ethanol-biodiesel-diesel). The addition of castor oil-derived biodiesel (COME) containing a high proportion of methyl ricinoleate (C18:1 OH) is an attractive approach in order to i) reduce the use of first generation biodiesel derived from edible sources, ii) balance the reduction in viscosity and lubricity of ethanol-diesel blends due to the high viscosity and excellent lubricity of methyl ricinoleate.