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A new generation of low heat capacitance Thermal Barrier Coatings (TBCs) has been developed under U.S. Dept. of Energy / Advanced Research Projects Agency - Energy (ARPA-E) sponsored research. The TBCs developed under this project have significantly lower thermal conductivity of < 0.35 W/m-K, thermal heat capacitance of < 500 kJ/m3-K, and density of <0.35 g/cm3. Two different binder types were used for thermal barrier coatings applied by High Velocity Low Pressure (HVLP) spraying to the piston, cylinder head, and valve combustion surfaces of a small natural gas engine. The effects of thermal barrier coatings on engine efficiency and knock characteristics were studied in a small, high compression ratio, spark-ignition, internal combustion engine operating on methane number fuels from 60 to 100. The new TBCs with low thermal conductivity and low thermal heat capacities have been shown to increase overall engine efficiency through reduced heat transfer to the piston and cylinder head.

This study looks at the application of a titanium dioxide (TiO2) catalytic nanoparticle suspension to the surface of the combustion chamber as a coating, as well as the addition of hydrogen gas to a four-stroke spark-ignited carbureted engine as a possible technique for lowering engine-out emissions. The experiments were conducted on two identical Generac gasoline powered generators using two, four and six halogen work lamps to load the engine. One generator was used as a control and the second had key components of the combustion chamber coated with the catalytic suspension. In addition to the coating, both engines were fed a hydrogen and oxygen gas mixture and tested at low, medium and high loads. Using an unmodified engine as a control set, the following three conditions were tested and compared: addition of hydrogen only, addition of coating only, and addition of hydrogen to the coated engine.