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The heat pump with low global warming potential (GWP) refrigerants is imperative for the electric vehicle (EV) to slow down global warming and extend the driving range while meeting passengers' thermal comfort in low ambient temperatures. However, there are no appropriate refrigerants. To provide long-term and environmental-friendly refrigerants in the heat pump for EVs, herein, we reported newly developed low-GWP refrigerant mixtures, i.e., DL3B, whose GWP is lower than 140, the flammability (lower flammability limit and burning velocity), saturation pressure, lubricant miscibility, material compatibility were experimentally tested. A test bench that can investigate the performance of an R410A prototype was built. The drop-in tests of the DL refrigerant were carried out to evaluate the capacities and COPs for both cooling and heating modes in the EV heat pump system.

An automobile heat pump system with conventional refrigerant (HFC-134a or HFO-1234yf) suffers significantly diminishment of heating capacity and system efficiency as the ambient temperature decreases. Natural refrigerant CO2 (GWP = 1) is considered as a promising alternative to HFC-134a in automobile air conditioning (MAC) applications with environmentally friendly advantage. In addition, CO2 automobile heat pump system is a promising heat pump technology for EVs with great heating advantages in a cold climate. This study aims to investigate the supercritical heat transfer characteristics of a compact micro-channel gas cooler applied in an automobile CO2 heat pump system. A simulation model of automobile gas cooler was developed by using segment-by-segment method, and validated by experimental results from Series Gas cooler (SGC) and One Gas cooler (OGC) CO2 heat pump systems. The error of heating capacity between calculated results and experimental results was less than 7%.

The electricity energy consumption for passenger cabin heating can drastically shorten the driving range for electric vehicles in cold climates. Mobile heat pump system is considered as an effective method to improve heating efficiency. This study investigates the system characteristics of mobile heat pump systems for electrical vehicle application. Based on KULI thermal management software, simulation models including HFC-R134a direct heat pump (DHP) and secondary loop heat pump (SLHP) were developed. The secondary loop employed in the SLHP includes a coolant pump, an indoor heater core and a plate heat exchanger, instead of an indoor condenser in the DHP. The use of a secondary loop has advantages to improve air outlet temperature uniformity. The simulation models were verified by measured data obtained from calorimeter experiments. By adopting simulation models, the effects of indoor and outdoor temperatures on system performance and cycle characteristics were discussed.

Two phase flow mal-distribution in inlet header of the parallel flow evaporator will cause performance degradation, partial frosting and comfortableness problems. In order to solve these issues in heat pump system of electric vehicles, four types of small diameter tube and fin heat exchangers with different flow passage were designed and experimental measured in heat pump system of electric vehicles. The experimental results showed that in terms of performance, the small diameter tube and fin heat exchanger can reach even exceed the micro-channel heat exchanger on capacity and COP in heating model. Compared with micro-channel, the tube and fin heat exchanger with 4 inlets and 4 outlets can increase capacity from 2010W to 2689W, and increase COP from 2.6 to 2.8. However the frost/defrost experimental results showed that there was a decrease on the capacity of micro-channel heat exchanger after several frost/defrost periods.