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Technical Paper

Rational Design of Cu-SSZ-13 Catalyst for the Selective Catalytic Reduction of NOx to Meet BS-VI Emission Standards

2021-09-22
2021-26-0181
To achieve healthier and sustainable air quality and to protect human life, worldwide emission standards are being tightened for harmful vehicular air pollutants such as CO, hydrocarbon, NOx and particulate matters. Among selective catalytic reduction catalysts for NOx control in automotive after treatment system, Cu-SSZ-13 (Chabazite structure) is one of the most promising SCR catalyst, mainly used in light and heavy duty diesel vehicles. This article focuses on the development of Cu-SSZ-13 with desired properties such crystallinity, morphology, surface area and Cu loading in the catalyst. With the help of sophisticated catalyst characterization tools such as NH3-Temperature Programmed Desorption (TPD), Temperature Programmed Reduction (TPR), BET surface area, X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM), novel and highly active formulations of Cu-SSZ-13 are reported here.
Journal Article

Low Temperature Selective Catalytic Reduction of NOx over Vanadium-Based Catalysts

2015-01-14
2015-26-0108
Diesel engines are becoming popular because of more fuel efficient and durability. While the CO and HC impurities are significantly lower than in gasoline engines, the design strategies for reduction of Particulate Matter and Nitrogen Oxides remain a major challenge for environment. The work mainly focused on reduction of NOx from diesel engines using SCR technology under Indian driving conditions and furl availability. With BS III/IV fuel available in the country, the catalyst system of choices the Vanadia Tungsten Titania (VWT) system because of its proven resistance to Sulfur poisoning. However, under urban driving conditions on Indian roads, the major obstacle is the low engine out temperatures which are below the normal operating temperature window (200 to 450 °C) of VWT - SCR.
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