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In recent years a new combustion phenomenon called Low-Speed Pre-Ignition (LSPI) occurred, which is the most important limiting factor to exploit further downsizing potential due to the associated peak pressures and thus the huge damage potential. In the past there were already several triggers for pre-ignitions identified, whereat engine oil seems to have an important influence. Other studies have reported that detached oil droplets from the piston crevice volume lead to auto-ignition prior to spark ignition. However, wall wetting and subsequently oil dilution and changes in the oil properties by impinging fuel on the cylinder wall seem to have a significant influence in terms of accumulation and detachment of oil-fuel droplets in the combustion chamber. For this reason, the influence of test fuels with different volatility were investigated in order to verify their influence on wall wetting, detachment and pre-ignition tendency.

In recent years concern has arisen over a new combustion anomaly, which was not commonly associated with naturally aspirated engines. This phenomenon referred to as Low-Speed Pre-Ignition (LSPI), which often leads to potentially damaging peak cylinder pressures, is the most important factor limiting further downsizing and the potential CO2 benefits that it could bring. Previous studies have identified several potential triggers for pre-ignition where engine oil seems to have an important influence. Many studies [1], [2] have reported that detached oil droplets from the piston crevice volume lead to auto-ignition prior to spark ignition. Furthermore, wall wetting and subsequently oil dilution [3] and changes in the oil properties by impinging fuel on the cylinder wall seem to have a significant influence in terms of accumulation and detachment of oil-fuel droplets in the combustion chamber.

Long-term reliability is one of the major requirements for the operation of automotive exhaust aftertreatment systems based on selective catalytic reduction (SCR). For an efficient reduction of nitrogen oxides in the SCR catalyst it is desirable that the thermolysis of the injected urea water solution (UWS) is completed within the mixing section of the exhaust system. Urea might undergo a number of secondary reactions leading to the formation of solid deposits on system walls. A deeper understanding of the mechanisms and influence factors is a basic requirement to prevent and predict undesired decomposition products. This paper outlines the mechanisms of UWS transport and deposition on a typical mixing element geometry. The conditions leading to deposit formation were investigated based on optical and temperature measurements in a box with optical access. A good correlation with the deposit location observed at the close-to-series exhaust system was found.