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The combustion efficiency of large gas engines is limited by knocking combustion. Due to fact that the quality of the fuel gas has a high impact on the self-ignition of the mixture, it is the aim of this work to model the knocking combustion for fuel gases with different composition using detailed chemistry. A cycle-resolved knock simulation of the fast burning cycles was carried out in order to assume realistic temperatures and pressures in the unburned mixture Therefore, an empirical model that predicts the cyclic variations on the basis of turbulent and chemical time scales was derived from measured burn rates and implemented in a 1D simulation model. Based on the simulation of the fast burning engine cycles the self-ignition process of the unburned zone was calculated with a stochastic reactor model and correlated to measurements from the engines test bench. A good agreement of the knock onset could be achieved with this approach.

The combustion of highly boosted gasoline engines is limited by knocking combustion and pre-ignition. Therefore, a comprehensive modelling approach consisting of cycle-to-cycle simulation, reactor modelling with detailed chemistry and CFD-simulation was used to predict the knock initiation and to identify the source of pre-ignition. A 4-cylinder DISI test engine was set up and operated at low engine speeds and high boost pressures in order to verify the accuracy of the numerical approach. The investigations showed that there is a correlation between the knocking combustion and the very first combustion phase. The onset of knock was simulated with a stochastic reactor model and detailed chemistry. In parallel, measurements with an optical spark plug were carried out in order to identify the location of knock onset. The simulation results were in good agreement with the measurements. Deposits and oil/fuel-droplets are possible triggers of pre-ignition.