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Within this study a dual-fuel concept was experimentally investigated. The utilized fuels were conventional EN228 RON95E10 and EN590 Diesel B7 pump fuels. The engine was a single cylinder Diesel research engine for passenger car application. Except for the installation of the port fuel injection valve, the engine was not modified. The investigated engine load range covered low part load operation of IMEP = 4.3 bar up to IMEP = 14.8 bar at different engine speeds. Investigations with Diesel pilot injection showed that the dual-fuel approach can significantly reduce the soot/NOx-trade-off, but typically increases the HC- and CO-emissions. At high engine load and gasoline mass fraction, the premixed gasoline/air self-ignited before Diesel fuel was injected. Reactivity Controlled Compression Ignition (RCCI) was subsequently investigated in a medium load point at IMEP = 6.8 bar.

A new index to evaluate the inherent soot reduction in a diesel-like spray plume is proposed in this study. The index is named “Oxidation Potential Number” and was derived with the help of a computational fluid dynamics (CFD) software. C8 - C16 n-alkanes, 1-alcohols and di-n-ethers were studied with the help of this index over four part load engine operating conditions, representative of a C-class diesel vehicle. The CFD modelling results have shown that C8 molecules feature a higher potentiality to reduce the soot. Thus, C8 molecules were tested in a single cylinder diesel engine over the same operating conditions. In conclusion, the proposed index is compared with the soot engine out emission.

This study investigated dual-fuel operation with a light duty Diesel engine over a wide engine load range. Ethanol was hereby injected into the intake duct, while Diesel was injected directly into the cylinder. At low loads, high ethanol shares are critical in terms of combustion stability and emissions of unburnt hydrocarbons. As the load increases, the rates of heat release become problematic with regard to noise and mechanical stress. At higher loads, an advanced injection of Diesel was found to be beneficial in terms of combustion noise and emissions. For all tests, engine-out NOx emissions were kept within the EU-6.1 limit.

The current and future restrictions on pollutant emissions from internal combustion engines require a holistic investigation of the abilities of alternative fuels to optimize the combustion process and ensure cleaner combustion. In this regard, the Tailor-made Fuels from Biomass (TMFB) Cluster at Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen University aims at designing production processes for biofuels as well as fuels optimal for use in internal combustion engines. The TMFB Cluster's scientific approach considers the molecular structure of the fuels as an additional degree of freedom for the optimization of both the production pathways and the combustion process of such novel biofuels. Thus, the model-based specification of target parameters is of the utmost importance to improve engine combustion performance and to send feedback information to the biofuel production process.

Future engines and vehicles will be required to reduce both regulated and CO2 emissions. To achieve this performance, they will be configured with advanced hardware and engine control technology that will enable their operation on a broader range of fuel properties than today. Previous work has shown that an advanced compression ignition bench engine can operate successfully on a European market gasoline over a range of speed/load conditions while achieving diesel-like engine efficiency and acceptable regulated emissions and noise levels. Stable Gasoline CI (GCI) combustion using a European market gasoline was achieved at high to medium engine loads but combustion at lower loads was very sensitive to EGR rates, leading to longer ignition delays and a steep cylinder pressure rise.

Legislative restrictions on the currently limited exhaust gas components and the future CO2 emissions limits have led to intensive research in the field of alternative fuels and innovative combustion approaches. Increased homogeneity of air-fuel mixture through advanced injection is one combustion approach, which potentially reduces engine-out nitrogen oxide and particulate emissions, with good fuel consumption in certain load ranges. Ignition characteristics under homogenous combustion conditions differ from those under heterogeneous conditions. Among other reasons, this is due to the increased role of low temperature chemistry with increasing homogeneity. The ignition behaviour of diesel fuels is characterised by the Cetane number (CN), which is, however, determined at significant higher temperatures than those prevalent during ignition under homogenous combustion. As a result, its relevance as a fuel characteristic number requires evaluation.

The residue and waste streams of existing industry offer feasible and sustainable raw materials for biofuel production. All kind of biomass contains carbon and hydrogen which can be turned into liquid form with suitable processes. Using hydrotreatment or Biomass-to-Liquid technologies (BTL) the liquid oil can be further converted into transportation biofuels. Hydrotreatment technology can be used to convert bio-oils and fats in to high quality diesel fuels that have superior fuel properties (e.g. low aromatic content and high cetane number) compared to regular diesel fuel and first generation ester-type diesel fuel. UPM has developed a new innovative technology based on hydrotreatment that can be used to convert Crude Tall Oil (CTO) into high quality renewable diesel fuel. This study concentrated on determining the functionality and possible effects of CTO based renewable diesel as a blending component on engine emissions and engine performance.

Demand for transport energy is growing but this growth is skewed heavily toward commercial transport, such as, heavy road, aviation, marine and rail which uses heavier fuels like diesel and kerosene. This is likely to lead to an abundance and easy availability of lighter fractions like naphtha, which is the product of the initial distillation of crude oil. Naphtha will also require lower energy to produce and hence will have a lower CO₂ impact compared to diesel or gasoline. It would be desirable to develop engine combustion systems that could run on naphtha. Many recent studies have shown that running compression ignition engines on very low Cetane fuels, which are very similar to naphtha in their auto-ignition behavior, offers the prospect of developing very efficient, clean, simple and cheap engine combustion systems. Significant development work would be required before such systems could power practical vehicles.

The current direction for Diesel combustion system development is towards homogenization, in order to reduce particulate and NOx emissions. However, a strong increase of carbon monoxide emissions (CO) is frequently noted in combination with enhanced homogenization. Therefore, the current investigation focuses on a detailed analysis of the particulate - CO trade-off using a laser-optical and multidimensional CFD investigation of the combustion process of a swirl HSDI system. The CFD methodology involves reduced kinetics for soot formation and oxidation and a three-step CO model. These models are validated by a detailed comparison to optical measurements of flow, spray penetration and the spatial distribution of soot, temperature and oxygen concentration. The results obtained show that high concentrations of CO occur as an intermediate combustion reaction product. Subsequently, CO and soot are oxidized in large areas of the combustion chamber.